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dulouz
Joined: 04 Feb 2003 Location: Uranus
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Posted: Sun Oct 30, 2005 1:55 am Post subject: Fun with alternative energy |
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Im always interested in alternative energy and its fuels. I go off the deep end for a few days and learn about its components. I was reading about aquaculture, a practic whereby plants are feed fish waste. Fish waste is the poo/feces but actually its the undigested waste plus ammonia.
I wanted to collect the ammonia and use it for cooling so you have vegetables, fish and AC.
There is some wishful thinking on behalf of the aquaculture folks in that the waste fert will be as a good as hydro ferts but it really can't be. If it works its by luck due the unpredictable nature of poo, natural ponds and various contaminents.
That being said, you need to hone the system enough to know whet you have. With animals, esp fish you get ammonia. Then how to capture it? You can distill it. After that you can use it for cooling.
Ammonia goes to liquid under pressure and vaporizes at lighter pressures. CO2 can be used to provide the pressure but thats kind of tricky.
So, you ferment to get ethanol. Ethanol runs the steam engine/ac generator for electricity. CO2 is used to help the plants. The fish make ammonia used for cooling without CFC's. |
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Wrench
Joined: 07 Apr 2005
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Posted: Sun Oct 30, 2005 4:20 am Post subject: |
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I think you would loose way to much energy converting the waste to get amonia. Unless use your urine for the amonia. |
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dulouz
Joined: 04 Feb 2003 Location: Uranus
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Posted: Sun Oct 30, 2005 3:34 pm Post subject: |
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Aquaculture can use fish but it can aslo use turtles. Turtles make plenty of ammonia or at least more than fish. I can smell the ammonia. The ammonia that is discharged from the animals reacts in the water. It breaks down but there is a saturation point where it can't react anymore so it escapes as gas. You can smell it then. I'd like to try to capture that. |
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mindmetoo
Joined: 02 Feb 2004
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Posted: Sun Oct 30, 2005 10:37 pm Post subject: |
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This web page has been around for a billion years and always an interesting stop:
Bill Beaty's famous "weird science" page:
http://www.amasci.com/weird.html |
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khyber
Joined: 16 Jan 2003 Location: Compunction Junction
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Posted: Thu Nov 03, 2005 8:16 am Post subject: |
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With animals, esp fish you get ammonia. Then how to capture it? You can distill it. After that you can use it for cooling. |
why not just boil the ammonia out of a solution of fish wastes and water (water and the waste having a higher boiling point than ammonia it'd be pretty damn easy really
isn't the boiling point of ammonia around 50C? that really wouldn't expend that much energy.
Then collect the gas.
Condense the gas again.
Then make a strong dilution.
doesn't seem that hard to me
But cooling? please dulouz tell me how ammonia cools; i'm quite curious
I had the misfortune of teaching my internship at this country school that had 3 of the saddest, poorly treated turtles i'd ever seen. Their tank was a 12x18x32 number with nothing but a single perch that was just half of the old lid of the tank. No one fed them and nobody cleaned their cages. We'd assign students but they didn't care..teacher? ditto.
So i ended up having to clean the thing out once a month. And that was some disGUSTing sheet.
I was told i would HAVE to wear gloves otherwise the water would severely harm my skin.
I shoulda done more for them damn turtles. like turtlenap them or something. |
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Bulsajo

Joined: 16 Jan 2003
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Posted: Thu Nov 03, 2005 8:31 am Post subject: |
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Anyone who has ever had an aquarium knows that amonia build up kills fish- it would be great to build some sort of balanced system whereby you could siphon or filter off the amonia before it reaches fish killing concentrations. Having to replace your entire fish populations doesn't sound very productive, and I imagine the whole idea would be to create something of a closed cycle that doesn't require the reintroduction of fish on a regular basis... pie in the sky: wouldn't it be great though to see dual-use (or more) aquariums sprouting up in every municipality? |
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dulouz
Joined: 04 Feb 2003 Location: Uranus
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Posted: Fri Nov 04, 2005 8:39 am Post subject: |
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But cooling? please dulouz tell me how ammonia cools; i'm quite curious |
Ammonia was one of the first refridgerants available.
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Ammonia has thermodynamic properties that make it very well suited as a refrigerant, since it liquefies readily under pressure, and was used in virtually all refrigeration units prior to the advent of haloalkanes such as Freon. However, ammonia is a toxic irritant and its corrosiveness to any copper alloys increases the risk that an undesirable leak may develop and cause a noxious hazard. Its use in small refrigeration units has been largely replaced by haloalkanes, which are not toxic irritants and are practically not flammable. (Note: Butane and isobutane, which have very suitable thermodynamic properties for refrigerants, are extremely flammable.) Ammonia continues to be used as a refrigerant in large industrial processes such as bulk icemaking and industrial food processing. Ammonia is also useful as a component in absorption-type refrigerators, which do not use compression and expansion cycles but can exploit heat differences. Since the implication of haloalkane being major contributors to ozone depletion, ammonia is again seeing increasing use as a refrigerant.
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If ammonia is a gas, what is that stuff they sell at the supermarket?
I also read that from fish wastes you are supposed to be able to make nitrous oxide. I want to read about that some more.
[url] http://en.wikipedia.org/wiki/Ammonia[/url]
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Ammonia is a colourless gas with a characteristic pungent smell; it is lighter than air, its density being 0.589 times that of air. It is easily liquefied and the liquid boils at -33.7 ��C, and solidifies at -75 ��C to a mass of white crystals. Liquid ammonia possesses strong ionizing powers (�� = 22), and solutions of salts in liquid ammonia have been much studied. Liquid ammonia has a very high standard enthalpy change of vaporization (23.35 kJ/mol, c.f. water 40.65 kJ/mol, methane 8.19 kJ/mol, phosphine 14.6 kJ/mol) and can therefore be used in laboratories in non-insulated vessels at room temperature, even though it is well above its boiling point.
It is miscible with water. All the ammonia contained in an aqueous solution of the gas may be expelled by boiling. The aqueous solution of ammonia is basic. The maximum concentration of ammonia in water (a saturated solution) has a density of 0.880 g cm-3 and is often known as '.880 Ammonia'.
It does not sustain combustion, and it does not burn readily unless mixed with oxygen, when it burns with a pale yellowish-green flame.
At high temperature and in the presence of a suitable catalyst, ammonia is decomposed into its constituent elements. Chlorine catches fire when passed into ammonia, forming nitrogen and hydrochloric acid; unless the ammonia is present in excess, the highly explosive nitrogen trichloride (NCl3) is also formed.
The ammonia molecule readily undergoes nitrogen inversion at normal pressures, that is to say that the nitrogen atom passes through the plane of the three hydrogen atoms as if it were an umbrella turning inside out in a strong wind. The energy barrier to this inversion is 24.7 kJ/mol in ammonia, and the resonance frequency is 23.79 GHz, corresponding to microwave radiation of a wavelength of 1.260 cm. The absorption at this frequency was the first microwave spectrum to be observed (C. E. Cleeton & N. H. Williams, 1934).
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Thats is for now, its 2 AM. I have to check out the chicks on the ave. |
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khyber
Joined: 16 Jan 2003 Location: Compunction Junction
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Posted: Mon Nov 07, 2005 12:22 am Post subject: |
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If ammonia is a gas, what is that stuff they sell at the supermarket? |
i never said ammonia was a gas but i did say that it was easy to boil out of water (as your link explains).
And therefore, to collect.
You could boil it right out of your fish water, collecting that and set up your own little refridgeration unit dulouz....buy a couple thousand gold fish; throw em in your backyard pool. Create an elaborate (periodic) pump, and boiling purification system. BLAM |
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dulouz
Joined: 04 Feb 2003 Location: Uranus
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Posted: Tue Nov 08, 2005 8:45 am Post subject: |
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Khyber,
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. It is easily liquefied and the liquid boils at -33.7 ��C |
Gosh, I don't know how to make a fire burn at -33.7C so it looks like boiling won't work.
Methinks ammonia works like this...
Aquatic animals poo out ammonia, some of that reacts with the water to make a less harmful compound. That reaction reaches equalibrium and the rest of the ammonia escapes as gas.
The collection process is sloppy. What should I do? Collect it in a big balloon?
I read that you can make Nitrous Oxide from urea. I wanna look at that too. |
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Bulsajo

Joined: 16 Jan 2003
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Posted: Tue Nov 08, 2005 8:53 am Post subject: |
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Methinks ammonia works like this...
Aquatic animals poo out ammonia, some of that reacts with the water to make a less harmful compound. That reaction reaches equalibrium and the rest of the ammonia escapes as gas. |
Check out home aquarium sites- most of them describe this process in detail (conversion of nitrites to nitrates, ammonia build up, etc.)
http://www.thetropicaltank.co.uk/bcycling.htm
http://www.thetropicaltank.co.uk/cycling2.htm |
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dulouz
Joined: 04 Feb 2003 Location: Uranus
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Posted: Tue Nov 08, 2005 9:14 am Post subject: |
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TY for the link
So it seems that if I want to have ammonia gas, I'd have to hurt the fish. I could use the turtles, they cope with ammonia much better. I need a chemical test for ammonia. |
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Bulsajo

Joined: 16 Jan 2003
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Posted: Tue Nov 08, 2005 10:07 am Post subject: |
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dulouz wrote: |
TY for the link
So it seems that if I want to have ammonia gas, I'd have to hurt the fish. I could use the turtles, they cope with ammonia much better. I need a chemical test for ammonia. |
And you'd need a heck of a lot of turtles!
The only commericail turtle farm that I'm aware of is the one for Green sea Turtles on Grand Cayman- they have a number of pools and tanks from hatchlings to 600 pound adults. And yeah, it smells exactly the way you think it does.
http://www.turtle.ky/main.cfm |
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dulouz
Joined: 04 Feb 2003 Location: Uranus
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Posted: Tue Nov 08, 2005 9:45 pm Post subject: |
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Buls, there are quite a few turtle farms in SE Asia but they are run by Chinese. The farms produce food turtles for export to Asia. They aren't nice places. I have a day dream about having one but since turtles take 8 years to mature enough to eat, its an awkward proposal.
The gov't or other bad people could seize the whole outfit on day 364 of the 7th year. I might want to put it in New Mexico or Louisiana. |
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keninseoul
Joined: 09 Mar 2004 Location: Seoul
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Posted: Thu Nov 17, 2005 7:32 pm Post subject: ammonia |
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I have NO idea how you would collect the gas from a fish farm - sounds rather impractical. The cost of a collection method would far exceed the cost of commercial ammonia - besides you use a closed system for cooling, so why bother with a continuous source.
You CAN collect manure from a livestock/poultry operation and run a bio-gas unit from it. The methane can run whatever; heater/cooking unit, or an ammonia fridge(!), though a steam engine would be impractical except for very large operations.
The effluent from the bio-gas makes great crop and aquatic fertilizer - significantly better than composed or aged manure.
I know of no cost-effective by-products from fish-farming save using the water for occasional partial irrigation or the fish by-products as animal feed or fertilizer.
I am planning an integrated farm in the tropics - have 9,000 sq m, currently used for rice.
Will engage in some cash crops and animal feed crops (by dedicated fields and by rotation). The animal feed crops will help feed the pigs. Pig manure will go to the bio-gas unit, etc - as above.
There is a smallish canal which runs thru the farm - planning on installing a small watermill to provide electricity for charging a battery bank. The batteries will provide power for lighting and light appliance use. Wind is not constant enough, nor strong enough (at my location) to consider it as a power source. Solar power is just too darn expensive, (from what I recall they are USD 8 to 12 a Watt) still, I did ask the PV companies in Korea, but none do retail. Too bad, Korea is so DIY backward. |
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